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Hydrogen or Electricity

Hydrogen seems to be the perfect energy carrier. Everything from heating, moving with a car and chemical processing should be powered by hydrogen. The idea of the hydrogen age is quite old and dates back to 19th century, when the great science fiction writer Jule Verne published 1874 the idea, that in the future, hydrogen will power everything we need.
"And what will they burn instead of coal?"
"Water," replied Harding.
"Water!" cried Pencroft, "water as fuel for steamers and engines! water to heat water!"
"Yes, but water decomposed into its primitive elements," replied Cyrus Harding, " Jules Verne, The Mysterious Island , 1874 [1]
Hydrogen was used for the first time to fill balloons (Source: Wikipedia)

Why are we still in the electricity age?

Electricity seems to be one of the greatest innovations, mankind ever made. Electricity has some advantages, which other technologies do not even come close to. Let me list some of them:
  • Speed of light: Electricity travels with the speed of light, and can be transmitted theoretically within a tenth of a second around the globe
  • No mass transportation involved: To transport electricity, we don't need to build trucks, railways or ships, because there is no mass during transportation present
  • Almost no conversion loss: To convert electricity into mechanical energy there is almost no loss, the efficiency in a modern electric motor is significantly higher than 90%
  • Multiple applications: Motion, light, information processing, heat, chemical reaction, sound, and unlimited other applications can be driven by electricity
  • No emission: This is a statement about electricity itself, not about the production of electricity.
  • Simple distribution even to the smallest applications with simple wires
  • No risk of explosion
Although the list of advantages is impressive, there is a hard problem remaining with electricity, and this is storage!

We have seen 100 years of research, but only a limited number of efficient storage concepts for electricity are available. Bulk storage is covered by pumped hydro systems, converting electrical energy into gravitational potential energy with a high efficiency of 80% during a roundtrip. Pumped hydro is therefore the absolutely preferred technology, when large amounts (GWh) of grid power have to be stored, in simple words 99% of grid storage is pumped hydro based. 

Small amounts of electricity in mobile devices from smartphone up to electric vehicles are powered by batteries of different types, preferred Li-Ion batteries.

Here comes Hydrogen

Every new concept of energy carrier needs at least some advantages over the previous one. Hydrogen has a big advantage, it is a storage concept for energy by itself. 

One kilogram of hydrogen contains 33 kWh of energy, if it is converted to water and we use the oxygen of the air and don't count the weight of the air. This number is the highest for any chemical, this is three times more energy than one liter diesel contains. But there is a problem, hydrogen is the gas with the least density, useful for balloons and Zeppelins. One liter of hydrogen at normal pressure contains only 0,003 kWh of energy and this is, without any discussion, insufficient for any application.

There are three ways to enhance the energy density of hydrogen per volume:
  • Pressurize: Typical modern storage systems have 700 Bar pressure (1,5 kWh/l)
  • Liquidity: At a temperature of -252 �C hydrogen gets liquid (2,8 kWh/l)
  • Hide in metals: some metals suck up hydrogen in their crystal grid 
All these techniques ad some significant weight and cost to the hydrogen and in addition it costs some energy to reach the dense state of the hydrogen. Typical loss is about 10% of the energy by the pressurizatio or cooling process.

In summary, storage of hydrogen is expensive but not prohibitively expensive.

Conversion to Hydrogen 

Hydrogen is an energy carrier, not an energy source as often cited. There is just no significant amount of free hydrogen on earth, so hydrogen has to be produced. The standard process of hydrogen production is steam reforming, using natural gas to produce hydrogen. This is by no means a sustainable solution.

To produce hydrogen for a sustainable energy future, it has to be produced with electricity from wind or solar sources. This is possible, but expensive. The core problem is, an electrolytic process, that disintegrates water molecules to hydrogen and oxygen by its very nature produces oxygen. We like oxygen for breathing, but metals don't, they imitatively corrode if oxygen and water are present. To get rid of this problem, we have to use noble metals like platinum or palladium and they are expensive.
Modern electrolytic cell for hydrogen production (Source: Wikipedia)
Another big problem is, the conversion of electricity energy into hydrogen comes not without losses. Depending on the details of the process, we end up at 20-30% loss of energy, a significant problem.

Distribution of Hydrogen

Transportation of hydrogen is preferably done by gas pipelines. A well known technology from natural gas, although not with the same efficiency, due to the very low density of the energy in even compressed hydrogen gas. Another problem is, hydrogen is a very small molecule that can travel even trough metal grids, so special care is necessary to use the right materials. 

Today, no country has a large hydrogen pipeline grid, resulting in the problem, it has to be built from scratch. And a pipeline grid is very expensive!

Using Hydrogen

At the end of the pipe, hydrogen has to be used in power consuming applications. The simple way to use it, is to burn hydrogen. It generates clean heat, only water is emitted into the air. Sounds perfect, but it doesn't make any sense, because using the electricity that generated the hydrogen could have been used in a radiator, this would be not only more energy efficient, it is also less dangerous.

Hydrogen engine in a BMW (source Wiki

Cars can use hydrogen as clean fuel. A slightly modified combustion engine can burn hydrogen, emitting water and some toxic nitrogen oxides, therefore we still need a catalyst at the exhaust pipe.
Another problem is the very low efficiency of a combustion engine, somewhere at 25% of the energy in the hydrogen reaches the road to accelerate the car. Resulting in a very low overall efficiency if we start with electricity. Compare this result to a Li-Ion battery, where about 90% of the energy reaches the road and as a bonus, we can reuse the energy when we brake to charge the battery again!

Another idea is, to convert the hydrogen back to electricity, whenever needed. This is possible, using a fuel cell. The sad thing about this part is, it comes again with high cost due to the expensive precious metals and with more loss of energy during conversion.

Is Hydrogen the Future?

Summing up all this points, today, an electric grid in combination with pumped hydro and batteries in mobile applications seems to be the better solution for the rising age of the renewable energy world.
But there is always research and no one can predict, if there is a breakthrough in technology. But this is not only true for hydrogen technologies, it is also true for batteries, pumped storage, e.g. the Hydraulic Rock Storage seems to be one, and many other technologies.  

Comment by Elon Musk to hydrogen

Confusing Hydrogen and Hydrogen

It should be mentioned, that there is a technology of nuclear fusion, using hydrogen to produce nuclear power. This path of research was not very promising till today, although a new interesting path, low energy nuclear reaction, commonly known as cold fusion might be a very disruptive technology, but this is another story.

References

[1] Jules Verne, The Mysterious Island, part 2, chapter 11, 1874


Fuel is Stored Solar Energy

We live in a world, where the energy we consume was stored eons ago by nature. The conversion efficiency of solar energy into oil was really lousy, only a fraction of the solar radiation was converted to biological mater, only a fraction was laid down into the ground and only a fraction is now available. If we do the math, we find, that less than one billionth (10E-9) of the solar energy, which reached the earth within the last 100 million years, is stored in our fuel resources. This leads to the idea that we can do better than nature!Using solar radiation energy conversion systems like photovoltaic or concentrated solar power, we end up near 20% conversion rate, which is sufficient for economic land use and by a factor of 100 better than plants, who only convert 0.1% of the energy in usable fibers or sugar. It should be mentioned, plants need water and solar cells love deserts! Resulting in no competition of land use if we are smart and don�t plant for energy but plant for food.

The Storage Problem Remains

There remains a problem, storage! Storage was never an easy business, but if solved it changed the world. Inventing hey for example was necessary to conquer the north hemisphere, where in winter time is no food for the livestock. Storing information in books was the breakthrough for the industrial age and unlimited computer storage capacity is essential for our information age.   

The upcoming renewable power age lacks of efficient and cheap storage capacity for electricity. Knowing this, we could visit the known technologies and there potential to solve the problem if further developed. Best known to the public are batteries. This is by the way a big problem, because our politicians, driven by their simple mind and the public, believe in batteries. Batteries are fine for mobile applications like cell phone and laptop. Cars using batteries are still expensive, but it may be within the reach of our technology to power them by batteries. Things get much more difficult, if we want to use batteries for grid scale applications.

Batteries are expensive, and need some more or less rare and expensive metals, they use processes which are not perfect rechargeable, this is the reason that batteries run out of business after a few thousand charging cycles. All this does not matter, if we use a mobile phone, live time is limited, the price of the battery is not the main value of the device and we don�t care to much on the environmental impact on the small scale that is involved.

Grid Scale Storage is Different

If we need storage for large scale, and grid technology is always about GW and TWh, values, which are trillion (10E12) times above the mobile phone and laptop scale. This is by the way easy to guess, as long as billions of consumers are out there. There are three different questions, how expensive is the storage capacity, how many times can we recharge it, and how efficient is the process. The reason why price matters is we can only earn a limited amount of money on every charging cycle. If the battery lifetime is already finished, before we have earned enough money to pay for the battery itself, it is useless to buy the battery at all.  The situation for the efficiency is in some way similar. If we have to pay more for the energy to charge the battery as we earn during discharge, the system doesn�t work either. The problem of efficiency is not the core problem of batteries, but of many other storage concepts. Batteries suffer from the price per storage capacity. 

Why Batteries don�t Work

Price of storage capacity for many batteries is above 200$/kWh, even for the very simple and widely used lead acid battery. Lithium based systems are often above 1000$/kWh although prices were dropping during the last two decades. Let�s do a simple calculation; our battery should be charged every day, as it makes sense in solar power systems. During nighttime the price of power should be 10ct/kWh more expensive as at daytime. If we discharge the battery, we earn 10ct every day and within six years we have a return of our investment into the lead acid battery. But this does not hold due to the fact, that our battery dies after about 1000 cycles. Using the Lithium system, things are even worse, we have to wait about 30 years for the return of our invest without any interest rate, this does not attract many investors.

More Storage Technologies

We visit other techniques of storage in the next blog posts

  • Methane
  • Pumped Hydro
  • Hydraulic Hydro Storage


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